
Enhanced Oil Recovery (EOR) has been getting a lot of attention lately in the media. There have been some who claim EOR will save the world from the pending Peak Oil anarchy and others who claim EOR, through carbon sequestration, will save the planet from the devastating effects of Global Warming. The purpose of this article is to give some basic insights into EOR, its benefits and limitations, and not to enter into the geopolitical debates.
In an earlier article I discussed water flooding and explained how a solution gas drive reservoir can benefit from water injection. In that discussion I mentioned through water flooding the oil recovery could reach as high as 40% of the Original Oil In Place (OOIP). Water flooding is commonly referred to as "secondary recovery" and despite this increase in oil recovered through secondary, there remains significant oil to be recovered through EOR, or "tertiary recovery." The additional oil recoverable through EOR varies widely, but an additional 10-25% OOIP is not uncommon.
There are several reasons that significant amounts of oil are left unrecovered in the reservoir even after large volumes of water may have been pumped through. All of these various causes are basically due to the properties of the oil itself and the fact that the oil is contained within the small pore spaces of a rock.
Oil is viscous, and some oils are extremely viscous and hard to displace. Oil and water don't mix on their own and this causes interfacial tension (drops of oil in water) which can be difficult to push through small pores, and in some cases the oil sticks directly to the rock itself (like when your old VW drips on the driveway, no matter how hard to try to hose it off you can't get it all). And, rocks themselves are not uniform and may contain streaks of high permeability which may allow displacing fluids to by-pass the oil. EOR processes have been designed to address these issues.
There are basically three categories of EOR: Chemical flooding, miscible displacement and thermal. Currently, according to the DOE, thermal accounts for more than 50% of the tertiary oil being produced in the US due in part to its wide use in the heavy oil fields of California, while miscible displacement makes up about 50% and chemical flooding is less than 1% (these are government numbers so we shouldn't neccessarily expect them to add up).
Thermal includes both steam flooding and fire flooding. The basic concept is to heat up the oil in the reservoir to lower its viscosity and allow the oil to flow more easily through the reservoir. In steam flooding, steam is injected through dedicated injection wells into the reservoir and the heated oil is displaced to a producing well just like a water flood (after all the steam becomes hot water once it cools a little). Fire flooding is a little different-- in this case oxygen is injected into the reservoir and ignited, burning some of the hydrocarbons and producing CO2 and water vapor (steam), and of course, heat. Thermal recovery processes are most beneficial in heavy oil (high viscosity) reservoirs.
Miscible displacement involves the injection of a substance that mixes with the oil in the reservoir to form a homogeneous mixture. The most widely injected substance in miscible flooding (and the one getting the most publicity) is CO2, but nitrogen and hydrocarbon gas are also being used. The basic concept is the mixing of the injected fluid with the oil alters the physical properties of the oil-- reduces its viscosity, lowers its surface tension and causes the oil to "swell." All of these things allow the oil to move more easily through the reservoir towards the producer.
Unfortunately, the injected fluid is much lighter and less viscous than the reservoir oil. This causes the injected fluid to want to "over run" and "finger" through the oil thus reducing the ability of the fluid to displace the oil in front of it. This problem has been addressed by alternating between injecting a slug of gas and a slug of water, followed by another slug of gas, and so on. This process is called WAG (water alternating gas) and has been very effective at controlling the gas in the reservoir.
Since the injected gas is mixed with the oil, it will inevitably be produced along with the oil. This is the limiting factor in relying on CO2 injection EOR for carbon sequestration. While some of the CO2 will remain in the reservoir and perhaps the reservoir could be filled with CO2 at the end of the flood's life, during the flood process CO2 is constantly being cycled through the reservoir and produced with the oil.
The third category of EOR is chemical flooding. Chemical flooding includes the injection of alkaline and polymers. Alkaline (soap) is used to remove the oil from the reservoir rock so that it can be displaced by the water flood, and polymers are used to "thicken" the water (increase its viscosity) so the water can better "sweep" the oil without fingering through (much as the WAG process is used in a CO2 flood). Also included in this category is the use of microbes. Microbes are either injected from an outside source or in situ microbes are fed and cultivated in the reservoir. The microbes are used to produce natural detergents and CO2 within the reservoir while building biomass within the pore spaces of the reservoir forcing the oil out.
Chemical flooding currently makes up a small portion of domestic EOR production, but there have been advances and more acceptance recently, especially in remote areas where miscible gases are not readily available or the size of the reservoir doesn't justify the investment required for other EOR methods.
EOR is a very important part of the life on an oil field; however, not every reservoir is a candidate for EOR for a variety of reasons, the most significant of which is economics. These processes are not inexpensive and typically require significant up-front capital investment. However, with the increasing trend in oil prices and the growing worldwide demand for oil, more and more oil fields will become viable candidates for EOR. As a wise man once said "The best place to find oil is in an oil field."